According to the documentation:
https://w3c.github.io/webdriver/#find-element-from-shadow-root step 2
https://w3c.github.io/webdriver/#find-elements-from-shadow-root step 2
the value for using has to be one of the Locator strategies table.
But for what I can see in https://dom.spec.whatwg.org/ there no method to get elements from a tag name in a shadow root.
Experimenting in Chromium and Firefox I can neither use xpath in a shadow root. For the xpath I'm not sure if is because is not defined in the standard or because they don't have it implemented, but right now is not supported.
For more context you can take a look to this thread in the WPT repository